A peanut-like Keggin-type POM-incorporated metal-organic framework

Hong-Ying Zang; Ke Tan; Ya-Qian Lan

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A peanut-like Keggin-type POM-incorporated metal-organic framework

机译：像花生一样的Keggin型POM掺入金属 - 有机框架

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摘要

A novel peanut-like POM-based metal-organic framework Cu3(BIMB)5(BIM)2(PMo_(12)O_(40))2 has been successfully constructed. The metal-organic framework forms a peanut-like shell and {PMo_(12)} anions embed in the voids to act as cores. The whole framework can be simplified as a (4,5)-connected 3D topology. In addition, we investigated the optical band gap of the title compound 2.84 eV.

机译：已成功构建了一种新型花生样POM基金属框架Cu3（BiMB）5（Bim）2（PMO_（12）O_（40））2。金属有机框架形成花生样壳，{PMO_（12）}阴离子嵌入空隙中以充当核心。整个框架可以被简化为（4,5）连接的3D拓扑。此外，我们研究了标题化合物2.84eV的光带隙。

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来源
《Inorganic Chemistry Communications》 |2010年第12期|共3页
作者
Hong-Ying Zang; Ke Tan; Ya-Qian Lan;
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作者单位

Institute of Functional Material Chemistry Key Lab of Polyoxometalate Science of Ministry of Education Faculty of Chemistry Northeast Normal University Changchun 130024 People's Republic of China;

Biological Scientific and Technical College Changchun University Changchun 130022 China;

Institute of Functional Material Chemistry Key Lab of Polyoxometalate Science of Ministry of Education Faculty of Chemistry Northeast Normal University Changchun 130024 People's Republic of China;

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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Polyoxometalates; Metal-organic cage; Cu~(II) complex; Optical band gap; Polyoxometalates (POMs);

机译：多氧化物;金属有机笼;Cu〜（ii）复合物;光带隙;多氧化物（POM）;

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专利

1. A peanut-like Keggin-type POM-incorporated metal-organic framework [J] . Hong-Ying Zang, Ke Tan, Ya-Qian Lan Inorganic Chemistry Communications . 2010,第12期

机译：像花生一样的Keggin型POM掺入金属 - 有机框架
2. Ionothermal Synthesis of Five Keggin-Type Polyoxometalate-Based Metal-Organic Frameworks [J] . Lu Kun, Pelaez Alex Liebman, Wu Luo-cheng, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019,第3期

机译：五克桂型多氧化胍基金属有机框架的离子液合成
3. Influence of pH, temperature, and alternating magnetic field on drug release from Keggin-type heteropoly acid encapsulated in iron-carboxylate nanoscale metal-organic framework [J] . Rafiee Ezzat, Nobakht Narges, Behbood Leila Research on Chemical Intermediates . 2017,第2期

机译：在铁 - 羧酸铁纳米金属 - 有机骨架中封装Keggin型杂多酸的pH，温度和交替磁场对药物释放的影响
4. Zeolites embrace metal-organic frameworks: building block approach to the design and synthesis of zeolite-like metal-organic frameworks (ZMOFs) [C] . Zehong Zhang, Fuyuan Liu, Yunwen Wang, 40th Anniversary of International Zeolite Conference;International Zeolite Conference . 2007

机译：沸石包含金属有机骨架：构造和合成类沸石金属有机骨架（ZMOF）的基础方法
5. Metal-organic Frameworks, including High-throughput Synthesis of Zeolitic Imidazolate Frameworks, and Their Applications in Carbon Dioxide Capture, Storage and as Catalysts for Methane Activation [D] . Phan, Anh Thi Phuong 2011

机译：金属有机骨架，包括高通量合成沸石咪唑酸酯骨架，及其在二氧化碳捕获，储存和甲烷活化催化剂中的应用
6. High-internal-phase emulsions stabilized by metal-organic frameworks and derivation of ultralight metal-organic aerogels [O] . Bingxing Zhang, Jianling Zhang, Chengcheng Liu, -1

机译：金属有机骨架稳定的高内相乳液和超轻金属有机气凝胶的衍生
7. Synthesis and catalytic properties of nickel salts of Keggin-type heteropolyacids embedded metal-organic framework hybrid nanocatalyst [O] . Qiuyun Zhang, Dan Ling, Dandan Lei, 2020

机译：Keggin型杂多酸嵌入式金属 - 有机骨架杂交纳米催化剂的合成与催化性能

A peanut-like Keggin-type POM-incorporated metal-organic framework

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