The first 1D tetranuclear organotin(IV) complex with N'-acylsalicylhydrazide: Synthesis, characterization and crystal structure

摘要

The first diorganotin(IV) complex 1 with N'-acylsalicylhydrazide has been successfully synthesized and structurally characterized by elemental analysis, FT-IR, NMR (~1H, ~(13)C and ~(119)Sn) spectra and X-ray crystallography. The complex 1 is an infinite 1D polymer with tetranuclear organotin(IV) as secondary building units, which contains five- and seven-coordinated tin atoms.