Synthesis, crystal structure and electrochemical properties of a novel tetranuclear silver(I) cluster based on l,l'-bis[(2-hydroxybenzylidene) thiocarbonohydrazono-1-ethyl] ferrocene (FcL)

Chun-Jie Qiao; Degang Ding; Jie Li

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Synthesis, crystal structure and electrochemical properties of a novel tetranuclear silver(I) cluster based on l,l'-bis[(2-hydroxybenzylidene) thiocarbonohydrazono-1-ethyl] ferrocene (FcL)

机译：基于L，L'-BIS [（2-羟基苄基）硫代羰基 - 1-乙基]二茂铁（FCL）新型四核银（I）簇的合成，晶体结构和电化学性能

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摘要

A novel tetranuclear silver(I) heterocyclic cluster, which is of nano-hole structure, based on 1,1'-bis[(2-hydroxybenzylidene)thiocarbonohydrazono-1-ethyl] ferrocene (FcL) has been prepared and structurally characterized by single-crystal X-ray diffractions. In addition, its electrochemical properties are also discussed. The results confirm that the receptor FcL is responsive to Ag~+.

机译：基于1,1'-BIS [（2-羟基苄基）硫代羰基芳基-1-乙基]二茂铁（FCL）的新型四核银（I）杂环簇是基于1,1'-BIS [（2-羟基苄基）-1-乙基]二甲苯-1-乙基]二碳烯（FCL），并通过单一表征 - 克里斯特X射线衍射。此外，还讨论了其电化学性质。结果证实，受体FCL对Ag〜+响应。

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来源
《Inorganic Chemistry Communications》 |2009年第10期|共4页
作者
Chun-Jie Qiao; Degang Ding; Jie Li;
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作者单位

Department of Chemistry Zhengzhou University Zhengzhou 450052 PR China;

Department of Chemistry Zhengzhou University Zhengzhou 450052 PR China;

Department of Chemistry Zhengzhou University Zhengzhou 450052 PR China;

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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Silver complex; Ferrocene derivative; Crystal structure; Electrochemical properties;

机译：银色复合物;二茂铁衍生物;晶体结构;电化学性质;

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1. Synthesis, crystal structure and electrochemical properties of a novel tetranuclear silver(I) cluster based on l,l'-bis[(2-hydroxybenzylidene) thiocarbonohydrazono-1-ethyl] ferrocene (FcL) [J] . Chun-Jie Qiao, Degang Ding, Jie Li Inorganic Chemistry Communications . 2009,第10期

机译：基于L，L'-BIS [（2-羟基苄基）硫代羰基 - 1-乙基]二茂铁（FCL）新型四核银（I）簇的合成，晶体结构和电化学性能
2. Functionalized ferrocenes and ferroceniums: synthesis, crystal structures and electrochemical properties based on carbazole/phenothiazine-ferrocene conjugated molecules [J] . Wang XC, Tian YP, Kan YH, Dalton transactions: An international journal of inorganic chemistry . 2009,第21期

机译：功能化的二茂铁和二茂铁鎓：基于咔唑/吩噻嗪-二茂铁共轭分子的合成，晶体结构和电化学性质
3. Synthesis, crystal structure and electrochemical behavior of tetranuclear transition metal clusters based on lacunary silicotungstates: [M4(H2O)2(SiW9O_(34))2]~(10-) (M = Ni~(2+), Co~(2+)) and [Fe4(μ-O)2(μ-OH)2(SiW_(10)O_(37))2]~(14-) [J] . Xia Zhao, Yang-Guang Li, Yong-Hui Wang Transition Metal Chemistry . 2008,第3期

机译：基于硅铝钨酸盐的四核过渡金属簇的合成，晶体结构和电化学行为：[M4（H2O）2（SiW9O_（34））2]〜（10-）（M = Ni〜（2+），Co〜（2 +））和[Fe4（μ-O）2（μ-OH）2（SiW_（10）O_（37））2]〜（14-）
4. Synthesis and physical properties of ferrocene derivatives XXIV: structural study of liquid crystalline mono-substituted ferrocene derivatives [C] . Naotake Nakamura, Kazuya Hiro, Kenjiro Uno Liquid crystals XIV . 2010

机译：二茂铁衍生物XXIV的合成和物理性质：液晶单取代二茂铁衍生物的结构研究
5. Synthesis and structure-property relationships of ferrocene-containing liquid crystals. [D] . Bhatt, Jayprakash C. 1991

机译：含二茂铁的液晶的合成及其结构-性质关系。
6. Synthesis and crystal and molecular structure of a tetranuclear cluster based on the rhenium(III)-bisorganohydrazino core: Re(HNNC4H3N2)(NNC4H3N2)(OCH3)24 [O] . Frank J. Femia, Xiaoyuan Chen, Kevin P. Maresca, -1

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机译：基于铼（III）-Bisorgano的氢芳基核的四核簇的合成和晶体结构：Re（HNNC4H3N2）（NNC4H3N2）（OCH3）2 4
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机译：Co（CO）4-与闭合金属羰基三聚体反应合成四核混合金属团簇。（ph3p）2NCoRu3（CO）13的晶体和分子结构

Synthesis, crystal structure and electrochemical properties of a novel tetranuclear silver(I) cluster based on l,l'-bis[(2-hydroxybenzylidene) thiocarbonohydrazono-1-ethyl] ferrocene (FcL)

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