Phase transformation controlled tetragonality of MnNi-based nanocrystals

摘要

The phase transformation controlled tetragonality of MnNi nanostructures has attracted wide interest for their shape memory effect. In this study, MnNi nanocrystals were selected to epitaxially grow an FeCo shell, where the antiferromagnetic 1(0) phase transformation of the MnNi core triggers the tetragonal distortion in the magnetically soft FeCo shell. The tetragonality change of L1(0) MnNi under thermal annealing enables the control of the tetragonality of the FeCo phase, ultimately increasing magnetocrystalline anisotropy and coercivity. This study opens up a new route to fabricate functional nanostructures with unique magnetic properties.