Controlled synthesis of transition metal/conducting polymer nanocomposites

摘要

A novel displacement reaction has been observed to occur between conducting polymers (CP) and metal salts which can be used to fabricate nanostructured CP-metal composites in a one-pot manner. Vanadium pentoxide (V_ 2O_ 5) nanofiber is used during the synthesis as the reactive seeds to induce the nanofibril CP-metal network formation. The CP-metal nanocomposites exhibit excellent sensory properties for hydrogen peroxide (H_ 2O_ 2) detection, where both high sensitivity and a low detection limit can be obtained. The sensory performance of the CP-metal composite can be further enhanced by a facile microwave treatment. It is believed that the CP-metal nanofibril network can be converted to a carbon-metal network by a microwave-induced carbonization process and result in the sensory enhancement.