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首页> 外文期刊>International Journal of Quantum Chemistry >The Rayleigh-Schr?dinger perturbation series of quasi-degenerate systems
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The Rayleigh-Schr?dinger perturbation series of quasi-degenerate systems

机译:拟简并系统的Rayleigh-Schr?dinger摄动序列

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摘要

We describe the first representation of the general term of the Rayleigh-Schr?dinger series for quasidegenerate systems. Each term of the series is represented by a tree and there is a straightforward relation between the tree and the analytical expression of the corresponding term. The combinatorial and graphical techniques used in the proof of the series expansion allow us to derive various resummation formulas of the series. A relation with several combinatorial objects used for special cases (degenerate or non-degenerate systems) is established.
机译:我们描述了准生成系统的Rayleigh-Schr?dinger级数的一般术语的第一个表示形式。该系列的每个术语都由一棵树表示,并且该树与相应术语的解析表达式之间存在直接的关系。在级数展开的证明中使用的组合和图形技术使我们能够导出级数的各种恢复公式。建立与用于特殊情况(退化或非退化系统)的几个组合对象的关系。

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