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首页> 外文期刊>International Journal of Quantum Chemistry >Spectral/structural data of helium atoms with exponential-cosine-screened coulomb potentials
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Spectral/structural data of helium atoms with exponential-cosine-screened coulomb potentials

机译:带有余弦筛选的库仑电势的氦原子的光谱/结构数据

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摘要

Atomic systems with exponential-cosine-screened Coulomb (ECSC) or static screened Coulomb (SSC) potentials have drawn considerable attention recently due to the possible applications to atoms in plasma environments. In this work, we develop a computing scheme to deal with the electron-electron correlation terms with the screened Coulomb interactions instead of the conventional expansion method using the Gegenbauer's addition theorem. Based on this approach, we investigate the helium atom with the ECSC potentials. Bypassing the complex expansion functions for electron-electron interactions, the proposed approach simplifies the calculations greatly and provides an advantage on programming. The results are found to be in good agreement with the existing data. Bound-state energies, oscillator strengths, and multipole polarizabilities varying with the screening parameters are presented. Comparisons of the ECSC potentials are made with the SSC potentials. The influence of screening effect on the energies, oscillator strengths, and polarizabilities is discussed. (c) 2015 Wiley Periodicals, Inc.
机译:由于在等离子体环境中可能应用于原子,具有指数余弦筛选的库仑(ECSC)或静态筛选的库仑(SSC)势的原子系统最近引起了相当大的关注。在这项工作中,我们开发了一种计算方案来处理具有筛选的库仑相互作用的电子-电子相关项,而不是使用Gegenbauer加法定理的传统扩展方法。基于这种方法,我们研究了具有ECSC电位的氦原子。绕开了电子-电子相互作用的复杂展开函数,该方法大大简化了计算,并为编程提供了优势。发现结果与现有数据非常吻合。提出了随着屏蔽参数而变化的束缚态能量,振荡器强度和多极极化率。 ECSC电位与SSC电位进行比较。讨论了屏蔽效应对能量,振荡器强度和极化率的影响。 (c)2015年威利期刊有限公司

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