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首页> 外文期刊>International Journal of Quantum Chemistry >High-lying core-excited quartet states in li-like N~(4+) and F ~(6+) ions
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High-lying core-excited quartet states in li-like N~(4+) and F ~(6+) ions

机译:锂样N〜(4+)和F〜(6+)离子中的高位核激发四重态

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摘要

The variational method with mutilconfiguration interaction wave function is used to obtain the energies, fine structures, and hyperfine structures of highlying core-excited quartet states 1s2|n|' 4P~o(m) (m = 1-5) and 1s2pnp ~4P(m) (m = 1-5) in Li-like N~(4+) and F~(6+) ions, including the mass polarization and relativistic corrections. Restricted variational method is carried out to extrapolate a better energy. The oscillator strengths, lifetime, wavelengths, fine structure, and hyperfine structure for this system are also investigated to compare with other theoretical and experimental data in the literature.
机译:使用具有多重配置相互作用波函数的变分方法来获得高度核心激发的四重态1s2 | n |'的能量,精细结构和超精细结构。 Li状N〜(4+)和F〜(6+)离子中的4P〜o(m)(m = 1-5)和1s2pnp〜4P(m)(m = 1-5),包括质量极化和相对论的更正。进行了受限的变分方法以推断出更好的能量。还研究了该系统的振荡器强度,寿命,波长,精细结构和超精细结构,以与文献中的其他理论和实验数据进行比较。

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