Donor-Stabilized 1,3-Disila-2,4-diazacyclobutadiene withaNonbonded Si center dot center dot center dot Si Distance Compressed to a Si=Si Double Bond Length

摘要

A donor-stabilized 1,3-disila-2,4-diazacyclobutadiene presents an exceptionally short nonbonded Si center dot center dot center dot Si distance (2.23 angstrom), which is as short as that of Si=Si bonds (2.15-2.23 angstrom). Theoretical investigations indicate that there is no bond between the two silicon atoms, and that the unusual geometry can be related to a significant coulomb repulsion between the two ring nitrogen atoms. This chemical pressure phenomenon could provide an alternative and superior way of squeezing out van der Waals space in highly strained structures, as compared to the classical physical methods.