Silver Complexes of Dihalogen Molecules

摘要

The perfluorohexane-soluble and donor-free silver compound Ag(A) (A= Al(ORF)(4); R-F = C(CF3)(3)) prepared using a facile novel route has unprecedented capabilities to form unusual and weakly bound complexes. Here, we report on the three dihalogen-silver complexes Ag(Cl-2)A, Ag(Br-2)A, and Ag(I-2)A derived from the soluble silver compound Ag(A) (characterized by single-crystal/powder XRD, Raman spectra, and quantum-mechanical calculations).