Transparent, Ultrahigh-Gas-Barrier Films with a Brick-Mortar-Sand Structure

摘要

Transparent and flexible gas-barrier materials have shown broad applications in electronics, food, and pharmaceutical preservation. Herein, we report ultrahigh-gas-barrier films with a brick-mortar-sand structure fabricated by layer-by-layer (LBL) assembly of XAl-layered double hydroxide (LDH, X=Mg, Ni, Zn, Co) nanoplatelets and polyacrylic acid (PAA) followed by CO2 infilling, denoted as (XAl-LDH/PAA)(n)-CO2. The near-perfectly parallel orientation of the LDH brick creates a long diffusion length to hinder the transmission of gas molecules in the PAA mortar. Most significantly, both the experimental studies and theoretical simulations reveal that the chemically adsorbed CO2 acts like sand to fill the free volume at the organic-inorganic interface, which further depresses the diffusion of permeating gas. The strategy presented here provides a new insight into the perception of barrier mechanism, and the (XAl-LDH/PAA)(n)-CO2 film is among the best gas barrier films ever reported.