The Methylsulfonyloxyl Radical, CH3SO3

Zhu Bifeng; Zeng Xiaoqing; Beckers Helmut; Francisco Joseph S.; Willner Helge

首页> 外文期刊>Angewandte Chemie >The Methylsulfonyloxyl Radical, CH3SO3

【24h】

The Methylsulfonyloxyl Radical, CH3SO3

机译：甲基磺酰氧基自由基CH3SO3

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The methylsulfonyloxyl radical, CH3SO3, one of the key intermediates in the atmospheric oxidation of dimethyl sulfide (DMS), was generated by flash pyrolysis of CH3SO2OOSO2CH3 and subsequently isolated in solid noble-gas matrices. The radical has been characterized by UV/Vis and IR spectroscopy and its tautomerization to CH2SO3H observed upon irradiation with light of lambda >= 360 nm.

机译：甲基磺酰氧基自由基CH3SO3是二甲基硫醚（DMS）大气氧化中的关键中间体之一，是通过CH3SO2OOSO2CH3的快速热解生成的，然后在固体稀有气体基质中进行分离。该自由基已通过UV / Vis和IR光谱进行了表征，并在λ> = 360 nm的光照射下观察到其互变异构为CH2SO3H。

著录项

来源
《Angewandte Chemie》 |2015年第39期|共6页
作者
Zhu Bifeng; Zeng Xiaoqing; Beckers Helmut; Francisco Joseph S.; Willner Helge;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
atmosphere chemistry; IR spectroscopy; photochemistry; radicals; UV/Vis spectroscopy;

机译：大气化学;红外光谱;光化学;基团;紫外/可见光谱;

相似文献

外文文献
中文文献
专利

1. The Methylsulfonyloxyl Radical, CH3SO3 [J] . Zhu Bifeng, Zeng Xiaoqing, Beckers Helmut, Angewandte Chemie . 2015,第39期

机译：甲基磺酰氧基自由基CH3SO3
2. One-pot multicomponent synthesis of 1,2,3,4-tetrasubstituted pyrroles catalyzed by [NMPH]CH3SO3 [J] . Pachechne Luana A., Pereira Vinicius F., Martins Guilherme M., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2019,第38期

机译：[NMPH] CH3SO3催化1,2,3,4-四氢吡咯的一锅多组分合成
3. The physicochemical properties of a room-temperature liquidus binary ionic liquid mixture of [HNMP][CH3SO3]/[Bmim]Cl and its application for fructose conversion to 5-hydroxymethylfurfural [J] . Xiao Yuyan, Huang Xirong RSC Advances . 2018,第34期

机译：[HNMP] [HNMP] [HN3SO3] / [Bmim] Cl的室温液相色素二元离子液体混合物的物理化学性质及其对5-羟甲基甲基糠醛的果糖转化的应用
4. What makes an Innovation Radical? Finding the 'radicalness' in radical innovation adoption [C] . Aditya Sharma, Dominic Thomas, Benn Konsynski 12th Americas Conference on Information Systems(AMCIS 2006) vol.2 . 2006

机译：是什么使创新激进？在根本性创新采用中找到“根基”
5. Kinetics Studies of Two Free Radicals, Amidogen Radical and Allyl Radical: Amidogen Radical(A2A1) Emission Lifetimes in the (0,9,0) and (0,8,0) Bands and Allyl Radical Reactions With Nitrogen Dioxide, Methyl Radical and Allyl Radical. [D] . N'Doumi, Marc. 2012

机译：两种自由基的动力学研究：酰胺基自由基和烯丙基自由基：（0,9,0）和（0,8,0）谱带中的酰胺基自由基（A2A1）发射寿命以及二氧化氮，甲基自由基和烯丙基的烯丙基自由基反应基。
6. Radical adducts of nitrosobenzene and 2-methyl-2-nitrosopropane with 1213-epoxylinoleic acid radical 1213-epoxylinolenic acid radical and 1415-epoxyarachidonic acid radical. Identification by h.p.l.c.-e.p.r. and liquid chromatography-thermospray-m.s. [O] . H Iwahashi, C E Parker, R P Mason, 1991

机译：亚硝基苯和2-甲基-2-亚硝基丙烷与1213-环氧亚油酸基1213-环氧亚麻酸基和1415-环氧花生四烯酸基的自由基加合物。通过h.p.l.c.-e.p.r.和液相色谱-热喷涂-m.s。
7. Synthesis, characterization and catalytic activity in the carbonylation of ethene of cis-Pd(H2O)2(PPh3)2X2 · nH2O (X=p-CH3C6H4SO3, n=2; X=CH3SO3, n=0). X-ray structure of cis-Pd(H2O)2(PPh3)2(p-CH3C6H4SO3)2 · 2H2O and of cis-Pd(H2O)2(PPh3)2(CH3SO3)2 · 2CH2Cl2 [O] . CAVINATO G, VAVASORI A, TONIOLO L., 2004

机译：顺式-Pd（H2O）2（PPh3）2 X2·nH2O（X = p-CH3C6H4SO3，n = 2; X = CH3SO3，n = 0）的合成，表征及羰基催化乙烯活性。顺式Pd（H2O）2（PPh3）2（p-CH3C6H4SO3）2·2H2O和顺式Pd（H2O）2（PPh3）2（CH3SO3）2·2CH2Cl2的X射线结构
8. Living/Controlled Radical Polymerization. Transition-Metal-Catalyzed AtomTransfer Radical Polymerization in the Presence of a Conventional Radical Initiator [R] . Wang, J. S., Matyjaszewski, K. 1995

机译：活性/可控自由基聚合。在常规自由基引发剂存在下的过渡金属催化的原子转移自由基聚合

The Methylsulfonyloxyl Radical, CH3SO3

摘要

著录项

相似文献

相关主题

期刊订阅