Tandem Catalytic C(sp(3))-H Amination/Sila-Sonogashira-Hagihara Coupling Reactions with Iodine Reagents

Buendia Julien; Darses Benjamin; Dauban Philippe

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Tandem Catalytic C(sp(3))-H Amination/Sila-Sonogashira-Hagihara Coupling Reactions with Iodine Reagents

机译：串联催化C（sp（3））-H胺化/ Sila-Sonogashira-Hagihara偶联反应与碘试剂

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A new tandem C-N and C-C bond-forming reaction has been achieved through Rh-II/Pd-0 catalysis. The sequence first involves an iodine(III) oxidant, then the in situ generated iodine(I) by-product is used as a coupling partner. The overall process demonstrates the synthetic value of iodoarenes produced in trivalent iodine reagent mediated oxidations.

机译：通过Rh-II / Pd-0催化，实现了新的串联C-N和C-C键形成反应。该序列首先涉及碘（III）氧化剂，然后将原位生成的碘（I）副产物用作偶联伴侣。整个过程证明了在三价碘试剂介导的氧化反应中产生的碘代芳烃的合成价值。

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《Angewandte Chemie》 |2015年第19期|共5页
作者
Buendia Julien; Darses Benjamin; Dauban Philippe;
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正文语种 eng
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关键词
C-H Activation; cross-coupling; homogeneous catalysis; hypervalent compounds; synthetic methods;

机译：碳氢活化交叉偶联均相催化高价化合物合成方法;

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专利

1. Tandem Catalytic C(sp(3))-H Amination/Sila-Sonogashira-Hagihara Coupling Reactions with Iodine Reagents [J] . Buendia Julien, Darses Benjamin, Dauban Philippe Angewandte Chemie . 2015,第19期

机译：串联催化C（sp（3））-H胺化/ Sila-Sonogashira-Hagihara偶联反应与碘试剂
2. Nondirected, Cu-Catalyzed sp(3) C-H Aminations with Hydroxylamine-Based Amination Reagents: Catalytic and Mechanistic Studies [J] . Wang Anqi, Venditto Nicholas J., Darcy Julia W., Organometallics . 2017,第7期

机译：具有羟胺基胺化试剂的Nondirected，Cu催化的SP（3）C-H辐射：催化和机械研究
3. Synthesis and Structure of Hypervalent Iodine(III) Reagents Containing Phthalimidate and Application to Oxidative Amination Reactions [J] . Kiyokawa Kensuke, Kosaka Tomoki, Kojima Takumi, Angewandte Chemie . 2015,第46期

机译：含邻苯二甲酰亚胺的超价碘（III）试剂的合成，结构及其在氧化胺化反应中的应用
4. Amination Reactions of 4-Alkyl-1,4-Dihydropyridines as Alkylation Reagents with Dialkyl Azodicarboxylates [C] . Yul in Zhang, Kazunari Nakajima, Yoshiaki Ni shibayashi 日本化学会春季年会講演予稿集 . 2018

机译：4-烷基-1,4-二氢吡啶作为烷基化试剂与二烷基氮杂羧酸盐的胺化反应
5. Part I. Acyl cyanide coupling reactions and the synthesis of β-tricarbonyl natural products. Part II. Oxidation of heteroatom-containing substrates with hypervalent iodine(V) reagents [D] . Mathison, Casey Jacob Nelson 2007

机译：第一部分：酰基氰偶联反应和β-三羰基天然产物的合成。第二部分用高价碘（V）试剂氧化含杂原子的底物
6. Nondirected Cu-Catalyzed sp3 C–H Aminations with Hydroxylamine-Based Amination Reagents: Catalytic and Mechanistic Studies [O] . Anqi Wang, Nicholas J. Venditto, Julia W. Darcy, -1

机译：基于羟基胺的胺化试剂对Cu催化的非定向铜sp3 C–H胺的催化和机理研究
7. Transition-Metal Catalyzed Cross-Coupling Reactions of Functionalized Organometallic Reagents, Nickel-Catalyzed Amination of Aryl Chlorides and Preparation and Reactions of Organozinc Reagents [O] . Manolikakes Georg 2009

机译：过渡金属催化的功能化有机金属试剂的交叉偶联反应，镍催化的芳酰氯胺化反应和有机锌试剂的反应

Tandem Catalytic C(sp(3))-H Amination/Sila-Sonogashira-Hagihara Coupling Reactions with Iodine Reagents

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