Rh-III-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection

Kim Ju Hyun; Gensch Tobias; Zhao Dongbing; Stegemann Linda; Strassert Cristian A.; Glorius Frank

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Rh-III-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection

机译：Rh-III催化的吡啶三唑活化C-H活化：直接进入荧光团进行金属离子检测

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The first CH bond activation with pyridotriazoles as coupling partners is presented using a Rh-III catalyst. The pyridotriazoles can be used as new carbene precursors in CH activation for direct access to novel fluorescent scaffolds. These tunable fluorophores can be applied for the detection of metalions.

机译：使用Rh-III催化剂进行了吡啶三唑作为偶联伙伴的首次CH键活化。吡啶三唑可在CH活化中用作新的卡宾前体，以直接使用新型荧光支架。这些可调荧光团可用于金属离子的检测。

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《Angewandte Chemie》 |2015年第37期|共5页
作者
Kim Ju Hyun; Gensch Tobias; Zhao Dongbing; Stegemann Linda; Strassert Cristian A.; Glorius Frank;
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正文语种 eng
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carbene; C-H activation; fluorophore; rhodium; triazole;

机译：卡宾;C-H活化;荧光团;铑;三唑;

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专利

1. Rh-III-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection [J] . Kim Ju Hyun, Gensch Tobias, Zhao Dongbing, Angewandte Chemie . 2015,第37期

机译：Rh-III催化的吡啶三唑活化C-H活化：直接进入荧光团进行金属离子检测
2. Annulation of beta-Enaminonitriles with Alkynes via Rh-III-Catalyzed C-H Activation: Direct Access to Highly Substituted 1-Naphthylamines and Naphtho[1,8-bc]pyridines [J] . Wang Haili, Xu Hong, Li Bin, Organic letters . 2018,第18期

机译：通过RH-III催化的C-H激活与炔烃的β-烯氨基腈的分套：直接进入高度取代的1-萘胺和萘吡啶[1,8-BC]吡啶
3. Rh-III-Catalyzed Dehydrogenative Coupling of Quinoline N-Oxides with Alkenes: N-Oxide as Traceless Directing Group for Remote C-H Activation [J] . Sharma Ritika, Kumar Rakesh, Kumar Inder, European journal of organic chemistry . 2015,第34期

机译：Rh-III催化的喹啉N-氧化物与烯烃的脱氢偶联：N-氧化物作为远程C-H活化的无痕导向基团
4. Effect on the 2-Heteroaryl Substituents as a Directing Group for thePalladium-catalyzed C-H Activation Arylation of Azulenes at the 1,3-Positions [C] . Yoshihiro Ogasawara, Takuya Nagasawa, Tomoaki Yatsu 日本化学会春季年会 . 2020

机译：对2-杂芳基取代基的影响为1,3位在1,3-位的丙啶催化的C-H活化芳族化的引导基团
5. 1, 2, 3-triazole as the Directing Group for Metal-Catalyzed C-H Activation. [D] . Ye, Xiaohan. 2015

机译：1，2，3-三唑作为金属催化C-H活化的指导基团。
6. Rhodium(III)-Catalyzed C-H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylic Acid [O] . Tyler A. Davis, Chuanqi Wang, Tomislav Rovis -1

机译：铑（III）催化的C H活化：羧酸指导的氧化分子内Heck型反应。
7. Orthopalladation of GFP-Like Fluorophores Through C-H Bond Activation: Scope and Photophysical Properties [O] . Sandra Collado, Alejandro Pueyo, Christine Baudequin, 2018

机译：通过C-H键活化的GFP样荧光团的正原孔：范围和光物理性质

Rh-III-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection

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