Isolation of a Non-Heteroatom-Stabilized Gold-Carbene Complex

摘要

Gold-carbene complexes are essential intermediates in many gold-catalyzed organic-synthetic transformations. While gold-carbene complexes with direct, vinylogous, or phenylogous heteroatom substitution have been synthesized and characterized, the. observation in the condensed phase of electronically non-stabilized gold-carbenes has so far remained elusive. The sterically extremely shielded, emerald-green complex [IPr Au = CMes2]~+[NTf2]~-has now been synthesized, isolated, and fully characterized. Its absorption maximum at 642 nm, in contrast to 528 nm of the red-purple carbocation [Mes2CH]~=, clearly demonstrates that gold is more than just a "soft proton".