A Chiral Phenoxyamine Magnesium Catalyst for tie Enantioselective Hydroaminatlon/Cyclization of Aminoalkenes and Intermolecular Hydroamination ofVinyl Arenes

摘要

The application of alkaline earth metal complexes as substitutes for transition-metal catalysts in alkene hydrofunc-tionalizations has drawn increasing attention in recent years owing to their abundance, biocompatibility, and chemical behavior, which resembles that of the rare-earth elements.