An Efficient and General Iron-Catalyzed C-C Bond Activation with 1,3-Dicarbonyl Units as a Leaving Groups

摘要

The substitution reaction is one of the fundamental reactions in chemistry and is widely applied in synthesis. Usually, a polarized and labile leaving group (LG), such as halides, tosylate, or psedohalides, is required for the success of a substitution reaction (Scheme 1). Recently, the use of carbon- based leaving groups through C—C bond cleavage has emerged as an attractive alternative in organic synthesis.