Nanoporous Nanorods Fabricated by Coordination Modulation and Oriented Attachment Growth

摘要

Well-designed metal-organic hybrid porous materials-so-called porous coordination polymers (PCPs) or metal-organic frameworks (MOFs)-can be made from an assembly of organic linkers with metal ions. This class of materials was recently recognized as an intriguing class of crystalline nanoporous materials for gas sorption, separation, and catalysis because their framework topologies and pore sizes can be designed for selective guest accommodation, and the functionality of the pore surfaces directly influences the interaction with guest molecules.