Palladium-Catalyzed Substitution of Allylic Fluorides

摘要

The chemistry of allylic fluorides has been intensively studied in recent years,with some emphasis on the preparation and reactions of enantiomerically pure examples.However,few cases of their participation in metal-catalyzed reactions are known.In pioneering work,Togni and co-workers explored the reactions of a model allyl fluoride with Pd and Pt complexes,and of cationic complexes of the same metals with desolvated fluoride ions.