Transient X-ray Diffraction Reveals Global and Major Reaction Pathways for the Photolysis of Iodoform in Solution

摘要

The understanding of reaction mechanisms requires detailed information about the processes that take place during the reactions.Various time-resolved optical spectroscopic tools have been developed to track such processes,and reaction dynamics can now be routinely investigated,with a time resolution of tens of femtoseconds,by using these optical techniques.Typical information provided by time-resolved spectroscopy includes the time constants of reaction intermediates and limited structural information.