Synthesis of 2,6-Diarylphenyldimethylsilyl Cations:Polar-jt Distribution of Cation Character

Simon Duttwyler; Quyen-Quyen Do; Anthony Linden

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Synthesis of 2,6-Diarylphenyldimethylsilyl Cations:Polar-jt Distribution of Cation Character

机译：2,6-二芳基苯基二甲基甲硅烷基阳离子的合成：阳离子特性的极性分布

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摘要

Discussion of the toluene solvate of the triethylsilyl cation brought to the fore the incredible reactivity of three-coordinate silyl cations and the ease with which they could be pacified by polar-pi(p-pi)interactions.

机译：对三乙基甲硅烷基阳离子的甲苯溶剂化物的讨论使三配位甲硅烷基阳离子具有令人难以置信的反应活性，并易于通过极性-pi（p-pi）相互作用来安抚它们。

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《Angewandte Chemie》 |2008年第9期|共4页
作者
Simon Duttwyler; Quyen-Quyen Do; Anthony Linden;
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正文语种 eng
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aromatic chemistry; Lewis acids; polar-re effects; silicon cations; stereochemistry;

机译：芳香化学;路易斯酸;极性反应;硅阳离子;立体化学;

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1. Synthesis of 2,6-Diarylphenyldimethylsilyl Cations:Polar-jt Distribution of Cation Character [J] . Simon Duttwyler, Quyen-Quyen Do, Anthony Linden Angewandte Chemie . 2008,第9期

机译：2,6-二芳基苯基二甲基甲硅烷基阳离子的合成：阳离子特性的极性分布
2. Synthesis, characterization and X-ray crystal structure of guanidinuim (pyridine-2,6-dicarboxylato)(pyridine-2,6-monocarboxylato) zincate(II) mono pyridine-2,6-dicarboxylic acid tetrahydrate [J] . Aghabozorg H, Sadr-Khanlou E Crystal Research and Technology: Journal of Experimental and Industrial Crystallography . 2008,第3期

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3. Stereoselective synthesis of 2,6-cis-and 2,6-trans-piperidines through organocatalytic aza-Michael reactions: A facile synthesis of (+)-myrtine and (-)-epimyrtine [J] . Ying Y., Kim H., Hong J. Organic letters . 2011,第4期

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4. Samarium Complexes from 2,6-Naphtalenedicarboxylate: Synthesis, Photocataiytic Properties and Degradation of Methylene Blue [C] . Dwi Aprillia Wulandari, Agustino Zulys, Eny Kusrini Annual Basic Science International Conference . 2019

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5. Oxidation of Organic Substrates in Aqueous Micellar Media Synthesis, Characterization and Application of N-alkyliminodiacetato Compounds for the Oxidation of Phenol and Carbon-Carbon Coupling of 2,6-di-tert-butylphenol in Aqueous Micellar Solutions. [D] . Cull, John Eli William. 2012

机译：胶束水溶液中有机底物的氧化胶束水溶液中2,6-二叔丁基苯酚的苯酚氧化和碳-碳偶联的N-烷基亚氨基二乙酰基化合物的合成，表征和应用。
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7. Enzyme Regulation in C4 Photosynthesis 1: Identification and Localization of Activities Catalyzing the Synthesis and Hydrolysis of Fructose-2,6-Bisphosphate in Corn Leaves [O] . Soll, Jürgen, Wötzel, Christiane, Buchanan, Bob B. 1985

机译：C4光合作用中的酶调节1：催化玉米叶片中2,6-二磷酸果糖的合成和水解的活性的鉴定和定位

Synthesis of 2,6-Diarylphenyldimethylsilyl Cations:Polar-jt Distribution of Cation Character

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