High-Pressure Polymorphism as a Step towards Destabilization of LiBH4

Yaroslav Filinchuk; Dmitry Chernyshov; Andriy Nevidomskyy

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High-Pressure Polymorphism as a Step towards Destabilization of LiBH4

机译：高压多态性使LiBH4不稳定

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摘要

Lithium borohydride could be an extremely efficient energy storage system containing 18.5 wt% hydrogen.However,owing to its high thermal stability,it is not yet regarded as a practical H-storage material.More experimental and theoretical efforts are required to improve the hydrogen-storage properties of this compound.

机译：硼氢化锂可能是一种非常有效的储氢系统，包含18.5 wt％的氢。但是，由于其高的热稳定性，它尚未被视为实用的H储藏材料。需要进行更多的实验和理论努力来改善氢-该化合物的储存性能。

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《Angewandte Chemie》 |2008年第3期|共4页
作者
Yaroslav Filinchuk; Dmitry Chernyshov; Andriy Nevidomskyy;
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正文语种 eng
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关键词
high pressure; hydrides; polymorphism; structure elucidation; X-ray diffraction;

机译：高压;氢化物;多态性;结构阐明;X射线衍射;

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专利

1. High-Pressure Polymorphism as a Step towards Destabilization of LiBH4 [J] . Yaroslav Filinchuk, Dmitry Chernyshov, Andriy Nevidomskyy Angewandte Chemie . 2008,第3期

机译：高压多态性使LiBH4不稳定
2. Achieving High Dehydrogenation Kinetics and Reversibility of LiBH4 by Adding Nanoporous h-BN to Destabilize LiH [J] . Zhu Jiuyi, Wang Hui, Liu Jiangwen, The journal of physical chemistry, C. Nanomaterials and interfaces . 2018,第41期

机译：通过添加纳米多孔H-BN来实现高脱氢动力学和LibH4的可逆性以使LIH稳定
3. Fluoride substitution in LiBH4; destabilization and decomposition [J] . Richter Bo, Ravnsbaek Dorthe B., Sharma Manish, Physical chemistry chemical physics: PCCP . 2017,第44期

机译：Libh4中的氟化物替代; 不稳定和分解
4. Significantly improved dehydrogenation and reversibility of LiBH4 destabilized by NbF5 [C] . Huaqin Kou, Yuanlin Zhou, Ge Sang World Hydrogen Energy Conference . 2014

机译：利用NBF5稳定地改善了Libh4的脱氢和可逆性
5. Twentieth-century American Gothic literature as cultural artifact: Science and technology as sources of destabilization in the fiction of H. P. Lovecraft, Richard Matheson, and Stephen King. [D] . Oakes, David Ashby. 1998

机译：二十世纪的美国哥特式文学作为文化人工制品：科学和技术是H. P. Lovecraft，Richard Matheson和Stephen King小说中破坏稳定的根源。
6. Tuning LiBH4 for Hydrogen Storage: Destabilization Additive and Nanoconfinement Approaches [O] . Julián Puszkiel, Aurelien Gasnier, Guillermina Amica, 2020

机译：调整LiBH4的储氢能力：去稳定添加和纳米约束方法
7. Tuning LiBH4 for Hydrogen Storage: Destabilization, Additive, and Nanoconfinement Approaches [O] . Julián Puszkiel, Aurelien Gasnier, Guillermina Amica, 2019

机译：调整LIBH4用于储氢：不稳定，添加剂和纳米罚法

High-Pressure Polymorphism as a Step towards Destabilization of LiBH4

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