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首页> 外文期刊>Angewandte Chemie >A Multi-Dimensional Microporous Silicate That Is Isomorphous to Zeolite MCM-68
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A Multi-Dimensional Microporous Silicate That Is Isomorphous to Zeolite MCM-68

机译:与沸石MCM-68同构的多维微孔硅酸盐

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摘要

Zeolites with large pores and multi-dimensional channel systems allow the diffusion of large molecules inside the pores.The number of zeolites with such characteristics is still limited,however,therefore the synthesis of new large-pore,multi-dimensional zeolites remains important.MCM-68(MSE topology)is a new type of multi-dimensional zeolite with a 12X10X10-membered ring(MR)pore system where a 12-MR straight channel intersects with two independent twisted 10-MR channels.This material also contains a super-cage(18X12-MR)that is accessible only through the 10-MR pores.
机译:具有大孔和多维通道系统的沸石允许大分子在孔内扩散。具有这种特性的沸石的数量仍然有限,因此,合成新的大孔,多维沸石仍然很重要。 -68(MSE拓扑)是一种新型的多维沸石,具有12X10X10元环(MR)孔系统,其中12MR直通道与两个独立的扭曲的10MR通道相交。只能通过10-MR孔进入的笼子(18X12-MR)。

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