Scaling Relationships for Adsorption Energies on Transition Metal Oxide,Sulfide,and Nitride Surfaces

摘要

There has been substantial progress in the description of adsorption and chemical reactions of simple molecules on transition-metal surfaces.Adsorption energies and activation energies have been obtained for a number of systems,and complete catalytic reactions have been described in some detail.Considerable progress has also been made in the theoretical description of the interaction of molecules with transition-metal oxides,sulfides,and nitrides,but it is considerably more complicated to describe such complex systems theoretically.