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首页> 外文期刊>Angewandte Chemie >Molecular Structure and Theoretical Studies of(PPh4)2[Bi_(10)Cu_(10)(SPh)_(24)]
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Molecular Structure and Theoretical Studies of(PPh4)2[Bi_(10)Cu_(10)(SPh)_(24)]

机译:(PPh4)2 [Bi_(10)Cu_(10)(SPh)_(24)]的分子结构和理论研究

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摘要

Transition-metal clusters containing main-group elements as bridging ligands have attracted our attention in recent years.In addition to many chalcogenide-bridged coinage-metal clusters,for example,[Cu_(146)Sc_(72)(PPh3)_(30)],[Ag_(262)S_(100)(StBu)_(62)-(dppb)](dppb = bis(diphenylphosphanyl)butane)and [Ag_(344)S_(124)(SrBu)_(96)],we have also reported the synthesis and characterization of a number of coinage-metal complexes containing Group 15 elements as ligands.
机译:近年来,以主族元素为桥联配体的过渡金属簇吸引了我们的注意。除了许多硫族化物桥连的造币金属簇之外,例如,[Cu_(146)Sc_(72)(PPh3)_(30 )],[Ag_(262)S_(100)(StBu)_(62)-(dppb)](dppb =双(二苯基膦基)丁烷)和[Ag_(344)S_(124)(SrBu)_(96) ],我们还报道了许多含有第15组元素作为配体的造币金属配合物的合成和表征。

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