Preparation and Characterization of Zinc Aluminosilicate Transparent Glass-Ceramics

摘要

Zinc aluminosilicate glasses containing Li_2O, ZnO, Al_2O_3 and SiO_2 were prepared by conventional melting and quenching technique, and subsequently converted to transparent glass-ceramics by controlled nucleation and crystallization. The glass was melted in a platinum crucible at 1 600 deg C for 2 h and then two-step heat treated for the nucleation and the crystal growth. The nucleation and crystallization temperatures were determined by differential thermal analysis. Specimens heat-treated on different schedules were analyzed by the X-ray diffraction to determine crystalline phases. Scanning electron microscopy was used to study the glass- ceramics morphology, the grain size and distribution in the residual glass matrix. The reorganization of the amorphous solid was confirmed by FT-IR spectroscopy. The transmittance was measured by a UV-Vis-NIR scanning spectrophotom-eter.