Raman spectroscopic detection for liquid and solid targets using a spatial heterodyne spectrometer

摘要

Spatial heterodyne Raman spectroscopy (SHRS) is a new type of effective method for the analysis of structure and composition of liquid and solid targets with the characteristics of no moving parts, high spectral resolution, high optical throughput and large field of view. The technique is very suitable for detecting the targets from long distances or under the conditions with ambient light, which is essential for the exploration of planetary surface. In order to have a better understanding of the ability of SHRS for the detection of liquid and solid targets, a breadboard was designed, built and calibrated. Signal to noise was estimated at different integration time or laser power for carbon tetrachloride. Pure materials or materials contained in bottles were both tested. The mixture of organic liquids or inorganic solids were tested. In order to test the detection ability for natural targets, some composition-unknown rocks and pebbles were tested. The results have shown that SHRS can meet the requirements for the detection of weak Raman signal scattered from artificial or natural targets. Standoff detection of sulfur from 5-m or 10-m distance without using any telescope or collimation optics was also tried to test the high optical throughput of SHRS. The potential feasibility of standoff detection has been proved. Copyright (c) 2015 John Wiley & Sons, Ltd.