首页> 外文期刊>Journal of chemical crystallography >Synthesis and crystal structure of a novel (mu-isothiocyanato) potassium complex with [Ni(en)(3)](2+) cation
【24h】

Synthesis and crystal structure of a novel (mu-isothiocyanato) potassium complex with [Ni(en)(3)](2+) cation

机译:[Ni(en)(3)](2+)阳离子新型(mu-isothiocyanato)钾配合物的合成和晶体结构

获取原文
获取原文并翻译 | 示例
获取外文期刊封面目录资料

摘要

A novel complex [K(NCS)(3)] center dot [Ni(N2C2H8)(3)] has been synthesized and characterized by X-ray diffraction. It crystalizes in trigonal system, and space group is P-3c1 with parameters: a = b = 11.6131(4) angstrom, c = 16.832(11) angstrom, gamma = 120, and Z = 4. The configuration of crystal consists of one [K(NCS)(3)](2-) ion and one [Ni(en)(3)](2+) cation. The potassium ion is located in the symmetry center and octahedrally coordinated by six nitrogen atoms, the adjacent potassium ions were connected into an infinite one-dimensional chain structure via the isothiocyanato group bridge ligand. There are significant weak intermolecular hydrogen bond intractions between the sulphur atom of the isothiocyanato group and the nitrogen atom of [Ni(en)(3)] moiety, and the complex can be viewed as an unusual corner-sharing one-dimensional extended polymer.
机译:合成了一种新型的配合物[K(NCS)(3)]中心点[Ni(N2C2H8)(3)],并通过X射线衍射对其进行了表征。它在三角系统中结晶,空间群为P-3c1,其参数为:a = b = 11.6131(4)埃,c = 16.832(11)埃,γ= 120,Z =4。晶体的结构由一个[K(NCS)(3)](2-)离子和一个[Ni(en)(3)](2+)阳离子。钾离子位于对称中心,由六个氮原子八面体配位,相邻的钾离子通过异硫氰酸根合桥配体连接成无限一维链状结构。异硫氰酸根合基团的硫原子与[Ni(en)(3)]部分的氮原子之间存在明显的弱分子间氢键吸引力,该配合物可被视为不寻常的角共享一维延伸聚合物。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号