Aging of hydrophobized surfaces of ramie fibers induced by atmospheric pressure plasma treatment with ethanol pretreatment

摘要

In order to investigate hydrophilic recovery of hydrophobic treatment of cellulose fibers, ramie fibers are ethanol-pretreated followed by atmospheric pressure plasma jet (APPJ) treatment using helium as the treatment gas and age for up to 150 days in 20 °C and 65% relative humidity. Scanning electron microscopy shows the fiber surfaces of the ethanol-pretreated+APPJ-treated group of freshly prepared, aged for 30 days, and aged for 150 days are covered with polypropylene matrix after fiber pullout tests. X-ray photoelec-tron spectroscopy shows that the freshly prepared ethanol-pretreated+APPJ-treated group has a 31% reduction in atomic ratio of oxygen to carbon and maintains at a similar level even after 150 days of aging. Water contact angle measurement demonstrates that the wettability of fiber surface of the freshly prepared ethanol-pretreated+APPJ-treated group drastically decreases and remains at the same lever after aging. Interfacial shear strength test reveals that the interfacial adhesion between PP matrix and ramie fiber for the freshly prepared ethanol-pretreated+APPJ-treated group increases 26% and remains substantially higher than that of the control group over time. These results indicate that the ethanol pretreatment followed by APPJ treatment is a permanent surface treatment with negligible aging for at least five months.