Preparation and Characterization of Bioblends from Gelatin and Linear Low Density Polyethylene (LLDPE) by Extrusion Method

摘要

Bioblends are composites of at least one biodegradable polymer with a non-biodegradable polymer. Successful development of bioblends requires that the biodegradable polymers be compatible with other component biodegradable/synthetic (non-biodegradable) polymers. Bioblends from LLDPE and gelatin were prepared by extrusion and hydraulic heat press technique. The gelatin content in the bioblends was varied from 5 to 20 wt%. Various physico-mechanical properties such as tensile, bending, impact strength (IS), thermal ageing and soil degradation properties of the LLDPE/gelatin bioblends with different gelatin contents were evaluated. The effect of thermal ageing on mechanical properties was studied. The mechanical properties such as tensile modulus (TM), bending strength (BS), bending modulus (BM) were found to increase with increasing gelatin content up to 20 wt%, however tensile strength (TS) and elongation at break (%E_b) were decreased with increasing gelatin content. Impact strength value increased with increasing gelatin content up to 10 wt% and then decreased slightly with increasing gelatin content. The blend containing 20 wt% gelatin showed relatively better mechanical properties than other blends. The values of TS, TM, %E_b, BS, BM and IS for the bioblend with 20 wt% gelatin content are 5.9 MPa, 206.3 MPa, 242.6%, 12.1 MPa, 8 MPa and 13.7 J/cm~2, respectively. Water uptake increases with increasing soaking time in water and weight loss due to soil burial also increases with increasing gelatin content in the blends but both are significantly lower than that of pure gelatin sheet. Weight loss values after thermal ageing increase with time, temperature and increasing gelatin content in the blend but are much lower than pure gelatin. Mechanical properties such as TS, TM are increased and %E_b is decreased after thermal ageing at 60℃ for 30 min. Consequently, among all of the bioblends prepared in this work the blend having 20% gelatin content yields properties such that it can be used as a semi-biodegradable material.