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A Translucent and Superhydrophobic Surface Prepared With a Sol-Gel Method Based on Alumina Nanoparticles

机译:基于氧化铝纳米粒子的溶胶-凝胶法制备的半透明超疏水表面

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摘要

A translucent and superhydrophobic surface was prepared with a sol-gel method on a glass substrate. The coating solution was obtained by hydrolysis of a chelate compound of aluminum isopropoxide and ethyl acetoacetate. Then, the films were prepared by dip-coating the glass substrates and subsequent surface modification with stearic acid. Field-emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), Fourier transform infrared (FT-IR) spectroscopy, UV-Vis spectroscopy, and contact angle (CA) measurements were used for the surface characterization. It was demonstrated that the coatings comprised a roughness structure on two levels with the root mean square roughnesses (R_(rms)) of ca. 30 and 200 nm, resulting in water static contact angle up to 168° and a small sliding angle of only 3°. The average visible light transmittance of the coatings was 62%.
机译:通过溶胶-凝胶法在玻璃基板上制备了半透明且超疏水的表面。通过水解异丙醇铝和乙酰乙酸乙酯的螯合物获得涂料溶液。然后,通过浸涂玻璃基板并随后用硬脂酸进行表面改性来制备膜。场发射扫描电子显微镜(FE-SEM),原子力显微镜(AFM),傅里叶变换红外(FT-IR)光谱,UV-Vis光谱和接触角(CA)测量用于表面表征。已证明涂层包含两个水平的粗糙度结构,均方根粗糙度(R_(rms))为ca。 30和200 nm,导致水的静态接触角高达168°,而滑动角仅为3°。涂层的平均可见光透射率为62%。

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