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Preparation, Morphology, and Properties of Organo-Montmorillonite/Nitrile Butadiene Rubber Nanocomposites

机译:有机蒙脱土/丁腈橡胶纳米复合材料的制备,形态和性能

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摘要

Organo-montmorilloniteitrile butadiene rubber (OMMT/NBR) nanocomposites were prepared by co-coagulating process, and then were combined with rubber ingredient and vulcanized by traditional rubber mixing procedure. The SEM micrographs of the nanocomposites showed uniform dispersion of the OMMT particles in NBR. The ATR-FTIR spectra illustrated the existence of montmorillonite in the nanocomposites. The XRD patterns further indicated the structure of nanocomposites, and confirmed an effective intercalation of NBR in the interlayer space of the OMMT. Moreover, the tensile strength and elongation at break of nanocomposites tended to increased rapidly with increasing OMMT loading, due to the reinforcing properties of OMMT to NBR. In addition, the TGA and DTA curves demonstrated the thermal performance of the nanocomposites enhanced. Furthermore, the addition of OMMT accelerated the vulcanization process.
机译:通过共混法制备有机蒙脱土/丁腈橡胶(OMMT / NBR)纳米复合材料,然后与橡胶成分混合,并通过传统的橡胶混合工艺进行硫化。纳米复合材料的SEM显微照片显示OMMT颗粒在NBR中均匀分散。 ATR-FTIR光谱说明了纳米复合物中存在蒙脱石。 XRD图谱进一步表明了纳米复合材料的结构,并证实了NBR在OMMT的层间空间中的有效嵌入。此外,由于OMMT对NBR的增强性能,随着OMMT载荷的增加,纳米复合材料的拉伸强度和断裂伸长率趋于迅速增加。此外,TGA和DTA曲线证明纳米复合材料的热性能得到增强。此外,OMMT的添加加快了硫化过程。

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