SYNTHESIS AND CRYSTAL STRUCTURE OF THE FIRST METALLABORANE CLUSTER CONTAINING THREE RINGS OF EXO-POLYHEDRAL CYCLIZATION

Dou JM.; Sun J.; Wei JD.; Zheng PJ.; Hu CH.

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SYNTHESIS AND CRYSTAL STRUCTURE OF THE FIRST METALLABORANE CLUSTER CONTAINING THREE RINGS OF EXO-POLYHEDRAL CYCLIZATION

机译：含外环多环化三环的第一茂金属硼烷簇的合成与晶体结构

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The novel nido 11-vertex nickelaborane [{mu-3,7-(PhCOS)}-{mu-7,8-(PhCOS)}-{mu-7,11-(PhCOS)}-10- PPh3-nido-7-NiB10H7] (1) was synthesized and characterized by X-ray diffraction analysis. This is the first metallaborane cluster that has three rings of exo-polyhedral cyclization. (C) 1997 Elsevier Science Ltd. [References: 14]

机译：新型nido 11-顶点镍硼烷[{mu-3,7-（PhCOS）}-{mu-7,8-（PhCOS）}-{mu-7,11-（PhCOS）}-10- PPh3-nido-合成7-NiB 10 H 7]（1），并通过X射线衍射分析进行表征。这是第一个具有三个外多面体环化环的金属硼烷簇。（C）1997 Elsevier Science Ltd. [参考：14]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1997年第21期|共3页
作者
Dou JM.; Sun J.; Wei JD.; Zheng PJ.; Hu CH.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Synthesis; Crystal structure; Metallaborane; Nickelaborane; Exo-polyhedral cyclization; Thiobenzoate; Molecular-structure; Chemistry; Vertices;

机译：合成;晶体结构;金属硼烷;镍硼烷;外多面环化;硫代苯甲酸酯;分子结构;化学;顶点;

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1. SYNTHESIS AND CRYSTAL STRUCTURE OF THE FIRST METALLABORANE CLUSTER CONTAINING THREE RINGS OF EXO-POLYHEDRAL CYCLIZATION [J] . Dou JM., Sun J., Wei JD., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1997,第21期

机译：含外环多环化三环的第一茂金属硼烷簇的合成与晶体结构
2. High-yield synthesis of a hybrid 2,3,4,5-tetracarba-1,6-nido-hexaborane(6) cluster with an exo-polyhedral boracycle [J] . Braunschweig H., Ghosh S., Kupfer T., Chemistry: A European journal . 2011,第15期

机译：具有外多面体硼环的杂化2,3,4,5-tetracarba-1,6-nido-hexaborane（6）簇的高产率合成
3. Preparation and characterization of macropolyhedral metallaborane clusters from the anti-B18H22 borane cluster: Crystal structure of [(CH3)(4)N][anti-B18H20Co(CO)(3)] [J] . Taylor JW., Englich U., Ruhlandt-Senge K., Organometallics . 2002,第14期

机译：从抗B18H22硼烷簇制备大面体金属多金属硼烷簇并进行表征：[（CH3）（4）N] [抗-B18H20Co（CO）（3）]的晶体结构
4. Selective Synthesis of Au_(20)Ag4M(SC2H4Ph)_(18) M=Pt or Pd Clusters and Determination of Their Geometric Structures by Single Crystal X-ray Diffraction Analysis [C] . Sakiat Hossain, Tasuku Ono, Mahiro Yoshioka 日本化学会春季年会講演予稿集 . 2018

机译：选择性合成AU_（20）Ag4m（SC2H4PH）_（18）M = Pt或Pd簇，并通过单晶X射线衍射分析测定它们的几何结构
5. Applications of samarium(II) iodide-promoted 8-membered ring cyclization reactions in natural product total synthesis: I. The total synthesis of (+)-isoschizandrin. II. Progress toward the total synthesis of variecolin. [D] . George, Kelly M. 2005

机译：碘化sa（II）促进的8元环环化反应在天然产物总合成中的应用：I.（+）-异五味子的总合成。二。向水杨素的全合成进展。
6. Synthesis crystal structures and properties of carbazole-based 6helicenes fused with an azine ring [O] . Daria I Tonkoglazova, Anna V Gulevskaya, Konstantin A Chistyakov, 2021

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7. Functionalized Metal Oxide Clusters: Synthesis, Characterization, Crystal Structures, and Magnetic Properties of a Novel Series of Fully Reduced Heteropolyoxovanadium Cationic Clusters Decorated with Organic LigandsMVIV6O6{(OCH2CH2)2N(CH2CH2OH)}6X (M = Li, X = ClLiCl; M = Na, X = ClH2O; M = Mg, X = 2BrH2O; M = Mn, Fe, X = 2Cl; M = Co, Ni, X = 2ClH2O) [O] . -1

机译：官能化金属氧化物簇：用有机Ligandsssssssssssssssmviv6o6（och2ch2）2n（ch 2ch2Oh）} 6x（m = li，x = cllicl; m = na，x = clh2o; m = mg，x = 2brh2o; m = mn，fe，x = 2cl; m = co，ni，x = 2clh2o）
8. Metallaborane Chemistry. Part 11.1 Lower Rotational Barriers in Seven-vertex than in Twelve-vertex Carbaplatinaboranes: Synthesis, and Molecular and Crystal Structures of (closo-1,1-(Et3P)2-2,3-Me2-1,2.3-PtC2B4H4) and (closo-1,1-( [R] . Barker, G. K., Green, M., Stone, F. G. A., 1979

机译：金属硼烷化学。第11.1部分七个顶点中的旋转障碍低于十二个顶点卡巴拉滨硼烷：（closo-1,1-（Et3p）2-2,3-me2-1,2.3-ptC2B4H4）的合成，分子和晶体结构和（闭合型1,1-（

SYNTHESIS AND CRYSTAL STRUCTURE OF THE FIRST METALLABORANE CLUSTER CONTAINING THREE RINGS OF EXO-POLYHEDRAL CYCLIZATION

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