A co-ordination number asymmetric dinuclear zinc(II) complex of an unsymmetrical compartmental proligand

Adams H.; Bradshaw D.; Fenton DE.

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A co-ordination number asymmetric dinuclear zinc(II) complex of an unsymmetrical compartmental proligand

机译：不对称区室配体的配位数不对称双核锌（II）配合物

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摘要

Reaction of the unsymmetrical compartmental proligand H2L3 with zinc(II) acetate and a counteranion to promote crystallisation has given the homodinuclear complexes [Zn2L3(OAc)(OH2)]X(.)nMeOH(.)mH(2)O [X = BF4, ClO4, PF6] which are co-ordination number asymmetric having present five- and six-co-ordinated zinc atoms. (C) 2002 Elsevier Science Ltd. All rights reserved. [References: 12]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2002年第19期|共4页
作者
Adams H.; Bradshaw D.; Fenton DE.;
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正文语种 eng
中图分类化学;
关键词
Crystal structures; Zinc(ii) complexes; Co-ordination number asymmetry; Active-site; Model; Ligands; Enzymes;

机译：晶体结构;锌（ii）配合物;配位数不对称;活性位;模型;配体;酶;

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1. A co-ordination number asymmetric dinuclear zinc(II) complex of an unsymmetrical compartmental proligand [J] . Adams H., Bradshaw D., Fenton DE. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2002,第19期

机译：不对称区室配体的配位数不对称双核锌（II）配合物
2. Dinuclear zinc(II) complexes of a [6,6]-unsymmetrical compartmental ligand [J] . Harry Adams, Laura R.Cummings, David E.Fenton, Inorganic Chemistry Communications . 2003,第1期

机译：[6,6]-不对称部分配体的双核锌（II）配合物
3. Dinuclear nickel(II) complexes of an unsymmetric "end-off" compartmental ligand: Conversion of urea into cyanate at a dinuclear nickel core [J] . Uozumi S., Ohba M., Okawa H., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第24期

机译：不对称的“末端”间隔配体的双核镍（II）配合物：双核镍核上尿素转化为氰酸酯
4. Dinuclear Zinc(II) complexes of linear and cyclic peptides containing two bis(2-pyridylmethyl)amino groups as catalysts for hydrolysis of RNA model substrate [C] . Masao Kawai, Hatsuo Yamamura, Nobuko Izuhara, the International Peptide Symposium . 2001

机译：二核锌（II）含有两个双（2-吡啶甲基）氨基的线性和环状肽的复合物作为用于水解RNA模型底物的催化剂
5. Mechanistic studies for transesterification of RNA analogues catalyzed by a dinuclear zinc(II) complex. [D] . Yang, Meng-Yin. 2007

机译：双核锌（II）配合物催化的RNA类似物酯交换反应的机理研究。
6. Asymmetric Dinuclear Lanthanide(III) Complexes from the Use of a Ligand Derived from 2-Acetylpyridine and Picolinoylhydrazide: Synthetic Structural and Magnetic Studies [O] . Diamantoula Maniaki, Panagiota S. Perlepe, Evangelos Pilichos, 2020

机译：来自使用衍生自2-乙酰吡啶和皮酚酰肼的配体的不对称二核镧系元素：合成结构和磁性研究
7. Facile high-yield synthesis of unsymmetric end-off compartmental double Schiff-base ligands: easy access to mononuclear precursor and unsymmetric dinuclear complexes [O] . Markus Schmidt, Helmar Görls, Winfried Plass 2016

机译：面部的高收益合成非对称的结尾隔层双席夫碱配体：轻松获得单核前体和非对称二维络合物
8. Synthesis and X-ray Crystal Structures of (Au(CH2)2PPh2)2(CF3)2, (Au(CH2)2PPh2)2(C6F5)2, and (PPN)(Au(C6F5)4): Two Dinuclear Gold (II) Ylide Complexes Containing Alkyl and Aryl Ligands and a Tetrakis(pentafluorophenyl)aurate(III) [R] . Murray, H. H., Fackler, J. P., Porter, L. C., 1987

机译：（au（CH2）2pph2）2（CF3）2，（au（CH2）2pph2）2（C6F5）2和（ppN）（au（C6F5）4）的合成和X射线晶体结构：两个双核金（ II）含有烷基和芳基配体的Ylide配合物和四（五氟苯基）丙酸酯（III）

A co-ordination number asymmetric dinuclear zinc(II) complex of an unsymmetrical compartmental proligand

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