Ferrocene-derived semicarbazones and thiosemicarbazones as ligands in heterobimetallic complexes with organotins. Crystal and molecular structures of formylferrocene-semicarbazonetrichlorophenyltin(IV) and of bis(acetylferrocenesemicarbazone)dichloro

摘要

The preparation and spectroscopic study of a series of ten heterobimetallic compounds containing Fe and Sn, in which ferrocenederived semicarbazones and thiosemicarbazones reacted with organotin acceptors of the RSnCl_3 and R_2SnCl_2 type, where R=CH_3, n-Bu and Ph, to give the final products is reported. The crystal and molecular structures of the two novel compounds formylferrocenesemicarbazonetrichlorophenyltin(IV) and bis(acetylferrocenesemicarbazone)dichlorodiphenyltin(IV) are also described.