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首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >SYNTHESIS, STRUCTURE AND PROPERTIES OF UNDECATUNGSTOZINCATE CONTAINING 3A ELEMENTS
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SYNTHESIS, STRUCTURE AND PROPERTIES OF UNDECATUNGSTOZINCATE CONTAINING 3A ELEMENTS

机译:含3A元素的低十价锌酸盐的合成,结构和性能

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摘要

New compounds KaHb[ZnW11O39M(H2O)]. xH(2)O (M = Al, Ga or In) were prepared and characterized by elemental analysis, IR and UV and Al-27 NMR spectroscopy, electrochemistry and X-ray crystallography. In the crystals of K6H3[ZnW11AlO40]. 9.5H(2)O, the anion is of the alpha-type Keggin structure with C-s symmetry. The Al and W atoms are statistically distributed in the crystal. (C) 1997 Elsevier Science Ltd. [References: 11]
机译:新化合物KaHb [ZnW11O39M(H2O)]。制备了xH(2)O(M = Al,Ga或In)并通过元素分析,IR和UV以及Al-27 NMR光谱,电化学和X射线晶体学进行了表征。在K6H3 [ZnW11AlO40]的晶体中。在9.5H(2)O中,阴离子为具有C-s对称性的α型Keggin结构。 Al和W原子统计地分布在晶体中。 (C)1997 Elsevier Science Ltd. [参考:11]

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