The mer-[RuCl_3(dppb)(H_2O)] complex: A versatile tool for synthesis of RuII compounds

摘要

The complex mer-[RuCl_3(dppb)(H_2O)] [dppb = 1,4-bis(diphenylphosphino)butane] was used as a precursor in the synthesis of the complexes tc-[RuCl_2(CO)_2(dppb)], ct-[RuCl _2(CO)_2(dppb)], cis-[RuCl_2(dppb)(Cl-bipy)], [RuCl(2Ac4mT)(dppb)] (2Ac4mT = N(4)-meta-tolyl-2-acetylpyridine thiosemicarbazone ion) and trans-[RuCl2(dppb)(mang)] (mang = mangiferin or 1,3,6,7-tetrahydroxyxanthone-C2-β-D-glucoside) complexes. For the synthesis of RuII complexes, the RuIII atom in mer-[RuCl_3(dppb)(H_2O)] may be reduced by H2(g), forming the intermediate [Ru_2Cl_4(dppb)_2], or by a ligand (such as H2Ac4mT or mangiferin). The X-ray structures of the cis-[RuCl_2(dppb)(Cl-bipy)], tc-[RuCl_2(CO) _2(dppb)] and [RuCl(2Ac4mT)(dppb)] complexes were determined.