Improving the use of mercury bis(phenyltellurolate) as efficient start for the synthesis of ternary clusters and polymers

摘要

Hg(TePh)(2) reacts with AgCl/PMe2Ph and AgClO4/PPh3 to give the ternary clusters [(PhTe)(4)Ag2Hg2(Cl)(2)](n) (1) and [(PhTe)(16)Ag(4)Hg(6)Py4]center dot H2O (2). While 1 assembles polymeric, bidimensional layers, 2 attains high symmetric moieties in which the occupational relationship is 40%/60% for the Ag+ and Hg2+ ions, respectively. (C) 2008 Elsevier Ltd. All rights reserved.