RUTHENIUM(II) COMPLEXES CONTAINING THE TRIDENTATE LIGAND 4,4'4''-TRI-TERT-BUTYL-TERPYRIDINE - SYNTHESIS AND ISOMERISATION STUDY OF TRANS-(TRPY-ASTERISK)RUCL2(L) [L=CO, PR(3), P(OR)(3)]

摘要

The synthesis and characterisation of a series of (trpy*)RuCl2(L) complexes [where trpy* = 4,4',4''-tri-tert-butyl-2,2'-6',2''-ter and L = CO, PPh(3), PMe(3), PMe(2)Ph, P(OPh)(3), P(OMe)3] are described together with a preliminary study of their trans --> cis thermal and photochemical isomerisation. [References: 10]