X-RAY CRYSTAL STRUCTURE, SPECTRAL AND MAGNETIC PROPERTIES OF A MIXED-LIGAND DINUCLEAR COMPLEX [CU(PHEN)(SA)(CLO4)](2)

摘要

The mixed-ligand dinuclear complex [Cu(Phen)(Sa)(ClO4)](2) (where Phen = 1,10-phenanthroline and Sa = salicylaldehyde) has been synthesized and characterized by IR and ESR spectra and magnetic susceptibility measurements, which obey the Curie-Weiss law with theta = -10 K. The crystal structure of the title complex has been determined and is a dimer in which two monomeric units are bridged by two oxygen atoms of phenolate groups. [References: 10]