THE OXIDATION OF OCTACYANOMOLYBDATE(IV) AND OCTACYANOTUNGSTATE(IV) BY NITROUS ACID

Dennis CR.; Basson SS.

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THE OXIDATION OF OCTACYANOMOLYBDATE(IV) AND OCTACYANOTUNGSTATE(IV) BY NITROUS ACID

机译：亚硝酸对八氯氰酸钼酸酯（IV）和八氯氰钨酸盐（IV）的氧化

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The kinetics of the oxidation of octacyanomolybdate(IV) by nitrous acid has been studied in aqueous perchloric acid medium. An equilibrium concentration of the nitrosonium ion, NO+, has been proposed as the active oxidizing species. An acid dissociation constant for H[Mo(CN)(8)](3-), K-a = 0.47 +/- 0.05 M at 25 degrees C and I = 1.0 M has been obtained from the kinetic data. (C) 1997 Elsevier Science Ltd. [References: 28]

机译：在高氯酸水溶液中研究了亚硝酸氧化八氰基钼酸盐（IV）的动力学。有人提出了一种平衡浓度的硝态氮离子NO +作为活性氧化物质。从动力学数据获得了H [Mo（CN）（8）]（3-）的酸解离常数，K-a = 25°C下的0.47 +/- 0.05 M，I = 1.0M。（C）1997 Elsevier Science Ltd. [参考：28]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1997年第21期|共4页
作者
Dennis CR.; Basson SS.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Octacyanomolybdate(iv); Octacyanotungstate(iv); Nitrous acid; Kinetics; Kinetics; Ions; Dihydrate;

机译：八氰基钼酸盐（iv）;八氰钨酸盐（iv）;亚硝酸;动力学;动力学;离子;二水合物;

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1. THE OXIDATION OF OCTACYANOMOLYBDATE(IV) AND OCTACYANOTUNGSTATE(IV) BY NITROUS ACID [J] . Dennis CR., Basson SS. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1997,第21期

机译：亚硝酸对八氯氰酸钼酸酯（IV）和八氯氰钨酸盐（IV）的氧化
2. Reaction products of titanium(IV) sulfate with the two, dimeric precursors, 1,2,3-tri-titanium(IV)- and 1,2-di-titanium(IV)-substituted α-Keggin polyoxometalates (POMs), under acidic conditions. A tetra-titanium(IV) oxide cluster and one coordinated sulfate ion grafted on a di-lacunary Keggin POM [J] . Kenji Nomiya, Yuki Mouri, Yoshitaka Sakai Inorganic Chemistry Communications . 2012,第Null期

机译：硫酸钛（IV）与两种二聚体前体1,2,3-三钛（IV）和1,2-二钛（IV）取代的α-Keggin多金属氧酸盐（POM）的反应产物酸性条件。四钛（IV）氧化物簇和一个配位的硫酸根离子接枝在双腔Keggin POM上
3. A revisit to the oxidation of the 12-tungstocobaltate(II) ion by permanganate ion and comparison with the oxidation of octacyanomolybdate (IV) ion [J] . Rupa Saha, Manu Mehrotra, Aditya Prakash, Indian Journal of Chemistry, Section A. Inorganic, Physical, Theoretical & Analytical . 2001,第8期

机译：通过高锰酸盐离子进行氧化12-钨钴酸盐（II）离子的氧化，并与辛辛醇钼酸盐（IV）离子的氧化相比
4. Synthesis and magnetic properties of octacyanotungstate-based magnet Mn~(II)Fe~(II)W~(IV)(CN)_8·8H_2O [C] . Yun He, Qing Lin, Jinpei Lin, Symposia on Electromagnetic and Electronic Engineering . 2015

机译：八辛酸锰镁基磁体Mn〜（II）Fe〜（II）W〜（IV）（CN）_8·8H_2O的合成和磁性
5. I. THE ELECTROCHEMISTRY OF NITRIC OXIDE AND A NITROUS ACID AT A MERCURY ELECTRODE IN AQUEOUS SOLUTIONS. II. ELECTROCHEMISTRY AND HYDROLYSIS KINETICS OF THE 2,2'-BIPYRIDINE COMPLEXES OF IRON(III) AND IRON(II); ELECTROCHEMICAL KINETIC PARAMETERS FOR SEVERAL IRON COMPLEXES. III. PROTON NUCLEAR MAGNETIC RESONANCE STUDIES OF URANIUM(IV)-ETHYLENE DIAMINETETRAACETIC ACID COMPLEXES IN AQUEOUS (DEUTERIUM-OXIDE) SOLUTIONS. [D] . EHMAN, DEWAYNE LEE. 1969

机译：I.水溶液中汞电极上一氧化二氮和亚硝酸的电化学二。铁（III）和铁（II）的2,2'-联吡啶络合物的电化学和水解动力学；多种铁络合物的电化学动力学参数。三，铀（IV）-水溶液（氧化氘）中铀（IV）-乙撑双氨基乙酸复合物的质子核磁共振研究
6. Transformation of Tri-Titanium(IV)-Substituted α-Keggin Polyoxometalate (POM) into Tetra-Titanium(IV)-Substituted POMs : Reaction Products of Titanium(IV) Sulfate with the Dimeric Keggin POM Precursor under Acidic Conditions [O] . Yuki Mouri, Yoshitaka Sakai, Yoshitaka Kobayashi, 2010

机译：三钛（IV）取代的α-Keggin多金属氧酸盐（POM）转变为四钛（IV）取代的POM：酸性条件下硫酸钛（IV）与二聚Keggin POM前体的反应产物
7. OXIDATION OF URANIUM(IV) BY OXYGEN AND NITROUS ACID [O] . Slade, A.L. 1961

机译：氧和亚硝酸氧化铀（Ⅳ）
8. OXIDATION OF URANIUM (IV) BY OXYGEN AND NITROUS ACID [R] . A. Laird Slade 1961

机译：氧和亚硝酸氧化铀（Ⅳ）

THE OXIDATION OF OCTACYANOMOLYBDATE(IV) AND OCTACYANOTUNGSTATE(IV) BY NITROUS ACID

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