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Glycolysis of polycarbonate wastes with microwave irradiation

机译:微波辐射对聚碳酸酯废料进行糖酵解

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摘要

Polycarbonate contained in waste compact discs have been glycolized with ethylene glycol using microwave irradiation in the presence of sodium hydroxide as catalyst in order to ob-tain bisphenol A (BPA) as the sole product. The influence of various parameters such as the concen-tration of the alkali metal catalyst and microwave irradiation power on product yield was studied in detail. The recovered BPA was analyzed with spectroscopic methods (~1H NMR, ~(13)C NMR, FT-IR) and the obtained results compared with staridards.
机译:为了获得作为唯一产品​​的双酚A(BPA),已在微波照射下,在氢氧化钠的存在下,用微波将乙二醇和废光盘中的聚碳酸酯进行了乙二醇化处理。详细研究了碱金属催化剂的浓度和微波辐射功率等各种参数对产物收率的影响。回收的双酚A用光谱法(〜1H NMR,〜(13)C NMR,FT-IR)分析,并将所得结果与标准品进行比较。

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