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Wplyw procesu wytlaczania z rozdmuchiwaniem folii z poliamidu na jej strukture i wlasciwosci

机译:聚酰胺吹膜挤出工艺对其结构和性能的影响

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摘要

The effect of the process of blowing extrusion of PA film on its structure and physical properties (measured by transmission microscopy, DSC, small angle light scattering, X-ray diffraction, IR spectroscopy) as well as mechanical properties at tension (Tables 3 and 4, Figs. 5-8) was characterized. The flow conditions affect (in complex way) the mechanisms causing molecular orientation of the molten plastic (Fig. 4) and the same way affect the mechanical properties. Strong bi-axial orientation of the film plane in comparison to the film thickness has been found. The reason of it is longitudinal drawing of the film sleeve. Lack of crosswise drawing is caused by negative degree f blow-up ratio. The orientation of macromolecules happens as a result of creation f the proper flow velocity gradients of the plastic, including strong lengthened flow at the enhanced relaxation time caused by lowering the temperature of plastic at the head nozzle. The analysis of experimental results show that film properties are strongly affected by the screw construction and extrusion conditions In the classic PA6 film blowing extrusion good mechanical properties the same time similar in both directors of the film sleeve can be obtained which is important in case of using the film sleeve for packaging purposes, e.g. as covers for cured meat products, where the film load in transversal direction can be twice more than in longitudinal one.
机译:吹膜过程对PA膜结构和物理性能(通过透射显微镜,DSC,小角度光散射,X射线衍射,IR光谱测量)以及拉伸时的机械性能的影响(表3和表4 ,图5-8)被表征。流动条件影响(以复杂的方式)导致熔融塑料分子取向的机理(图4),并且以相同的方式影响机械性能。已经发现,与膜厚度相比,膜平面的强双轴取向。其原因是薄膜套筒的纵向拉伸。负拉伸度f引起横向拉伸不足。大分子的取向是通过产生适当的塑料流速梯度而产生的,包括在喷头喷嘴处降低塑料温度而导致的弛豫时间延长,流动延长。对实验结果的分析表明,膜的性能受螺杆结构和挤出条件的影响很大。在经典的PA6吹膜挤出中,良好的机械性能可同时获得膜套两个导向器的相似性能,这在使用时非常重要。用于包装目的的薄膜套,例如作为腌制肉制品的覆盖层,横向的薄膜负载可能是纵向薄膜的两倍。

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