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Effect of urea, sodium nitrate and ethylene glycol addition on the rheological properties of corn starch pastes

机译:尿素,硝酸钠和乙二醇的添加对玉米淀粉糊流变特性的影响

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摘要

The effects of the additives used in starch adhesives production on the pasting process and rheological properties of native corn starch were investigated. Suspensions of the starch of Indentata variety (6 %) prepared in distilled water or aqueous solutions of urea (2.5 %), sodium nitrate(V) (2.5 %) and ethylene glycol (1.5 %) were subjected to a controlled pasting in RVA viscometer. The obtained pastes were placed in a measuring cylinder of HAAKE rheometer and the viscosity measurements were performed using controlled shear rate (CR) mode at shear rates of 0-600 s(-1). The paste smears were analyzed under a microscope after staining with Lugol's solution. It was found that the addition of urea caused a reduction in the pasting temperature, change in the shape of pasting curve as well as 30 % increase in the final viscosity (Table 1). The addition of sodium nitrate(V) led to an increase in the pasting time, decrease of the viscosity drop and reduced viscosity increase during cooling (Fig. 1). The influence of ethylene glycol additive on the pasting process was less significant than that of urea and sodium nitrate(V). Corn starch forms pastes or shear thinning suspensions with a distinct change in the rheological properties over time.
机译:研究了用于淀粉胶粘剂生产中的添加剂对天然玉米淀粉糊化过程和流变性的影响。在蒸馏水或尿素(2.5%),硝酸钠(V)(2.5%)和乙二醇(1.5%)的蒸馏水或尿素水溶液中制备的Indentata淀粉(6%)的悬浮液在RVA粘度计中进行受控糊化。将获得的糊状物放置在HAAKE流变仪的量筒中,并使用受控剪切速率(CR)模式在0-600 s(-1)的剪切速率下进行粘度测量。用Lugol溶液染色后,在显微镜下分析糊状涂片。发现添加尿素导致糊化温度降低,糊化曲线形状改变以及最终粘度增加30%(表1)。硝酸钠(V)的添加导致糊化时间的增加,粘度下降的减少和冷却过程中粘度增加的减少(图1)。乙二醇添加剂对糊化过程的影响不如尿素和硝酸钠(V)大。玉米淀粉形成糊状或剪切稀化的悬浮液,其流变性随时间发生明显变化。

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