Pyrolysis of whole wood chips and rods in a novel ablative reactor

摘要

The ability to carry out pyrolysis, of entire wood chips and rods instead of small particles would be of great value for mobile pyrolysis units, because of the large possible savings in grinding costs (7-9% of total process costs). With this goal in mind, we designed and constructed a novel lab-scale ablative reactor for fast pyrolysis of entire wood chips and even wood rods, converting those directly into a high yield of bio-oil for the first time. The bio-oil yield from fast pyrolysis of wood chips (10 x 20 mm) was as high as 60 wt.%, similar to that from wood crumbles (2 x 2 mm). Additionally, the yield and composition of bio-oil from ablative pyrolysis were in the same range as those obtained from a fluidized bed reactor using <1 mm particles, with the small differences (slightly lower yield and HHV, and higher water content) attributed to the longer vapor residence times in the ablative reactor, which promote secondary reactions. We modeled the heat transfer characteristics of this semi-batch system, and comparison with experimental measurements confirmed that radiation from the hot components does not significantly decompose the wood prior to direct contact with the hot metallic surface in ablative pyrolysis. The findings of this work have the potential to lead to new developments for small-scale, mobile pyrolysis units for the disposal of forest residues. (C) 2017 Elsevier Ltd. All rights reserved.