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One-dimensional Chained Polymer Constructed by 3-Indolepropionic acid and 2,2'-Bipyridinium

机译:由3-吲哚丙酸和2,2'-双吡啶构成的一维链链聚合物

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The crystals of one-dimensional chained polymer constructed by 3-indolepropionic acid and 2,2'-bipyridinium have been synthesized by evaporation from ethanol solution. The crystal structure of one-dimensional chained polymer was determined by X-ray single crystal diffraction analysis. The results shows that the polymer belongs to monoclinic, space group P2(1)/c, a = 5.2557(11) A, b = 12.249(2) A, c = 21.467(4) A, V = 1380.1(5) A~3, Z = 2, Mr = 531.58, De = 1.279 g/cm~3, T = 293(2) K, F (000) = 558, R = 0.1136 and wR = 0.3376. The compound forms one-dimensional chained polymer through hydrogen bonds. 3D network structure was constructed by the interaction of the one-dimensional chained polymer.
机译:通过从乙醇溶液中蒸发合成由3-吲哚丙酸和2,2'-双吡啶构成的一维链链聚合物的晶体。通过X射线单晶衍射分析测定一维链链的晶体结构。结果表明,该聚合物属于单斜,空间组P2(1)/ C,a = 5.2557(11)A,B = 12.249(2)A,C = 21.467(4)A,V = 1380.1(5)a 〜3,Z = 2,MR = 531.58,DE = 1.279g / cm〜3,T = 293(2)k,f(000)= 558,r = 0.1136和WR = 0.3376。该化合物通过氢键形成一维链链的聚合物。通过一维链链的聚合物的相互作用构建了3D网络结构。

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