Pitting Studies Under Anoxic Conditions on Candidate Container Materials AISI316L hMo and UHB 904L for The Disposal of HLW in Argillaceous Formations

摘要

Stainless steel is being envisaged as the primary candidate container material for the final disposal of vitrified HLW in deep geological argillaceous formations in Belgium. The impact of an evolving underground repository environment, i.e. a progressive change from oxic to anoxic conditions (due to the consumption of entrapped oxygen), on the pitting behaviour of austenitic stainless steels AISI 316L hMo and UHB 904L was studied. CPP-experiments were performed in synthetic solutions, which are representative for the near-field chemistry of an underground repository. The solutions contained various amounts of Cl~-(100-50,000 mg/L) at near-neutral pH. Experiments were conducted at 16 and 90°C. AISI 316L hMo and UHB 904L will not be subjected to immediate pitting problems neither under oxic, nor under anoxic conditions. However, AISI 316LhMo could present long-term pitting problems under oxic conditions. Pits are much easier initiated on AISI 316L hMo, for both oxic and anoxic conditions. The pits propagate in a rather similar manner under oxic conditions for both alloys, whereas under anoxic conditions the pits formed on AISI 316L hMo are much deeper. AISI 316L hMo is more susceptible to crevice attack..