An Oxidation System for Green Chemistry ― Synthesis of Bi-Metallic Schiff Base Complexes and Oxidation of Phenols in the Presence of the Complexes ―

摘要

Bimetallic copper complexes were synthesized from the schiff bases which were obtained by the reaction between bis(3-aminophenyl) sulphone and salicylaldehyde and the derivatives in order to clarify the active site of the immobilized polymer catalyst. The complex-H_2O_2 system showed effective oxiation of phenols. The active site was elucidated by UV spectrum.