摘要:
The self-assembly reactions of MⅡCl2 (M = Ni, Co) with the flexible bix ligand [bix = 1,4-bis(imidazole-1-ylmethyl)benzene] yielded a 2D network [NⅢ(bix)2Cl2]n 1 and a 1D chain [CoⅡ(bix)Cl2]n 2. Their crystal structures have been determined by X-ray single-crystal diffraction analysis. Complex 1 characters a two-dimensional grid-type structure and crystallizes in monoclinic, space group P21/c with a = 7.7231(7), b = 12.7787(9), c = 13.9374(13)(A), β = 105.419(4)°, C28H28Cl2N8Ni, Mr = 606.19, Ζ = 2, V = 1326.0(2)(A)3, Dc = 1.518 g/cm3, μ = 0.969 mm-1, F(000) = 628, R = 0.0429 and wR = 0.0783 for 2503 observed reflections (Ⅰ> 2σ(Ⅰ)). Compound 2 is a one-dimensional chain and crystallizes in orthorhombic, space group Pbca with a = 11.3696(6), b = 10.2128(6), c = 14.4943(9) (A), C14H14Cl2CoN4, Mr = 368.12, Z = 4, V = 1683.01(17)(A)3, Dc = 1.453 g/cm3, μ = 1.334 mm-1, F(000) = 748, R = 0.0317 and wR = 0.0800 for 1778 observed reflections (Ⅰ> 2σ(Ⅰ)). Magnetic properties of the title complexes were also investigated.