thin film

摘要： Thermoelectric devices enable direct conversion between thermal and electrical energy.Recent studies have indicated that the thin film/substrate heterostructure is effective in achieving high thermoelectric performance via decoupling the Seebeck coefficient and electrical conductivity otherwise adversely inter-dependent in homogenous bulk materials.However,the mechanism underlying the thin film/substrate heterostructure thermoelectricity remains unclear.In addition,the power output of the thin film/substrate heterostructure is limited to the nanowatt scale to date,falling short of the practical application requirement.Here,we fabricated the CrN/SrTiO_(3-x) heterostructures with high thermoelectric output power and outstanding thermal stability.By varying the CrN film thickness and the reduction degree of CrN/SrTiO_(3-x) substrate,the optimized power output and the power density have respectively reached 276μWand 10^(8) mW/cm^(2) for the 30 nm CrN film on a highly reduced surface of CrN/SrTiO_(3-x) under a temperature difference of 300 K.The performance enhancement is attributed to the CrN/CrN/SrTiO_(3-x) heterointerface,corroborated by the band bending as revealed by the scanning Kelvin probe microscopy.These results will stimulate further research efforts towards interface thermoelectrics.

摘要： In this review,the application of light ion irradiation is discussed for tailoring novel functional materials and for improving the performance in SiC or Si based electrical power devices.The deep traps and electronic disorder produced by light ion irradiation can modify the electrical,magnetic,and optical properties of films(e.g.,dilute ferromagnetic semiconductors and topological materials).Additionally,benefiting from the high reproducibility,precise manipulation of functional depth and density of defects,as well as the flexible patternability,the helium or proton ion irradiation has been successfully employed in improving the dynamic performance of SiC and Si based PiN diode power devices by reducing their majority carrier lifetime,although the static performance is sacrificed due to deep level traps.Such a trade-off has been regarded as the key point to compromise the static and dynamic performances of power devices.As a result,herein the light ion irradiation is highlighted in both exploring new physics and optimizing the performance in functional materials and electrical devices.

摘要： The present work presents a study of forced convection condensation of a laminar film of a pure and saturated vapor on a porous plate inclined to the vertical. The Darcy-Brinkman-Forchheimer model is used to write the flow in the porous medium, while the classical boundary layer equations have been exploited in the pure liquid and in the porous medium taking into account inertia and enthalpy convection terms. The problem has been solved numerically. The results are mainly presented in the form of velocity and temperature profiles. The obtained results have been compared with the numerical results of Chaynane et al. [1]. The effects of different influential parameters such as: inclination (ϕ), effective viscosity (ReK), and dimensionless thermal conductivity λ* on the flow and heat transfers are outlined.

摘要： The retarded kinetics of oxygen evolution on electrodes is a bottleneck for electrochemical energy conversion and storage systems.NiFe-based electrocatalysts provide a cost-effective choice to confront this challenge.However,there is a lack of facile techniques for depositing compact catalytic films of high coverage and possessing a state-of-the-art performance,which is especially desired in photoelectrochemical(PEC)systems.Herein,we demonstrate a spray pyrolysis(SP)route to address this issue,featuring the kinetic selective preparation towards the desired catalytic-active material.Differing from reported SP protocols which only produce inactive oxides,this approach directly generates a unique composite film consisting of NiFe layered oxyhydroxides and amorphous oxides,exhibiting an overpotential as small as 255 mV(10 mA cm^(−2))and a turnover frequency of∼0.4 s^(−1)per metal atom.By using such a facile protocol,the surface rate-limiting issue of BiVO_(4)photoanodes can be effectively resolved,resulting in a charge injection efficiency of over 90%.Considering this deposition directly start from simple nitrates but only takes several seconds to complete,we believe it can be developed as a widely applicable and welcomed functionalization technique for diverse electrochemical devices.

摘要： This work reviews technologies that can be used to develop low-temperature solid oxide cells(LT-SOCs)and can be applied in fuel cells and electrolyzers operating at temperatures below 500°C,thus providing a more cost-effective alternative than conventional high-temperature SOCs.Two routes showing potential to reduce the operating temperature of SOCs to below 500°C are discussed.The first route is the principal way to enhance cell performance,namely,structure optimization.This technique includes the reduction of electrolyte thickness to the nanometer scale and the exploration of electrode structure with low polarization resistance.The other route is the development of novel protonconducting electrolyte materials,which is in the frontier of SOCs study.The fundamentals of proton conduction and the design principles of commonly used electrolyte materials are briefly explained.The most widely studied electrolyte materials for LT-SOCs,namely,perovskitetype BaCeO_(3) -and BaZrO_(3) -based oxides,and the effect of doping on the physical-chemical properties of these oxide materials are summarized.

摘要： All-solid-state thin-film lithium batteries(TFLBs)are the ideal wireless power sources for on-chip micro/nanodevices due to the significant advantages of safety,portability,and integration.As the bottleneck for increasing the energy density of TFLBs,the key components of cathode,electrolyte,and anode are still underway to be improved.In this review,a brief history of TFLBs is first outlined by presenting several TFLB configurations.Based on the state-of-the-art materials developed for lithium-ion batteries(LIBs),the challenges and related strategies for the application of those potential electrode and electrolyte materials in TFLBs are discussed.Given the advanced manufacture and characterization techniques,the recent advances of TFLBs are reviewed for pursuing the high-energy-density and long-termdurability demands,which could guide the development of future TFLBs and analogous all-solid-state lithium batteries.

摘要： The numerical study of thin film type condensation in forced convection of a saturated pure vapor in an inclined wall covered with a porous material is presented. The generalized Darcy-Brinkman-Forchheimer (DBF) model is used to describe the flow in the porous medium while the classical boundary layer equations have been exploited in the case of a pure liquid. The dimensionless equations are solved by an implicit finite difference method and the iterative Gauss-Seidel method. The objective of this study is to examine the influence of the Prandtl number on the hydrodynamic and thermal fields but also on the local Nusselt number and on the boundary layer thickness. For Pr ≤ 0.7 (low) the velocity and the longitudinal temperature increase with the Prandtl number. On the other hand, when Pr ≥ 2 (high) the Prandtl number no longer influences the velocity and the longitudinal temperature. The local Nusselt number increases as the Prandtl number increases and the thickness of the hydrodynamic boundary layer increases as the Prandtl number decreases.

摘要： In this work, we propose an original approach to the thin-layer identification of secondary metabolites (terpenes) based on the acquisition of multicomponent images integrating terpenes to be identified. Its principle consists initially of segmentation by region of each component of the image based on the attribute tuples or colors of each region of the digital image. Then we proceeded to the calculations of region parameters such as standard deviation, entropy, average pixel color, eccentricity from an algorithm on the matlab software. These values allowed us to build a database. Finally, we built an algorithm for identifying secondary metabolites (terpenes) on the basis of these data. The relevance of our method of identifying or recognizing terpenes has been demonstrated compared to other methods, such as the one based on the calculation of frontal ratios which cannot discriminate between two terpenes having the same frontal ratio. The robustness of our method with respect to the identification of linalool, limonene was tested.

摘要： The study of forced convection in a porous medium has aroused and still arouses today the interest of many scientists and industrialists. A considerable amount of work has been undertaken following the discovery of the phenomenon. Solving a standard problem of forced convection in porous media comes down to predicting the temperature and velocity fields as well as the intensity of the flow as a function of the various parameters of the problem. A numerical study of the condensation in forced convection of a pure and saturated vapor on a vertical wall covered with a porous material is presented. The transfers in the porous medium and the liquid film are described respectively by the Darcy-Brinkman model and the classical boundary layer equations. The dimensionless equations are solved by an implicit finite difference method and the iterative Gauss-Seidel method. Our study makes it possible to examine and highlight the role of parameters such as: the Froude number and the thickness of the porous layer on the speed and the temperature in the porous medium. Given the objective of our study, the presentation of velocity and temperature profiles is limited in the porous medium. The results show that the Froude number does not influence the thermal field. The temperature increases with an increase in the thickness of the dimensionless porous layer. The decrease in the Froude number leads to an increase in the hydrodynamic field.

摘要： With the advent of new materials, microchip industry is investigating new architecture to further scale down the device size. New technologies are on the way to achieving this goal without compromising with the device’s performance and benefits. In this new scenario, corona charge deposition technique (CCDT) has become an indispensable part of the thin film industry. Due to the non-invasive and non-destructive nature of corona charge ions, they are effectively being used to improve the device properties. They are also useful to understand the electrical properties of insulators and other materials. Corona-Kelvin non-contact metrology or the C-KM is the most recent development in this field. In this review, the applications of corona charge deposition technique in the semiconductor industry have been reviewed. Further, the methodology involved is described. The advances as well as challenges and improvements including the future research are also discussed.